Crystal Structure Determination of the Nonclassical 2-Norbornyl Cation-Reference-Cited by-同舟云学术

Crystal Structure Determination of the Nonclassical 2-Norbornyl Cation

Published:2013-07-05 Issue:6141 Volume:341 Page:62-64
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Scholz F.¹,Himmel D.¹,Heinemann F. W.²,Schleyer P. v. R.³⁴,Meyer K.²,Krossing I.¹

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg, Germany.

2. Department of Chemistry and Pharmacy, Inorganic Chemistry, Friedrich-Alexander-University Erlangen-Nuremberg, Egerlandstrasse 1, 91058 Erlangen, Germany.

3. Department of Chemistry, University of Georgia, Athens, GA 30602, USA.

4. Department of Organic Chemistry, University of Erlangen-Nuremberg, Henkestraße 42, 91054 Erlangen, Germany.

Abstract

A Nonclassical Conclusion The concept of valence, which underlies the Periodic Table, originated in studies of reactivity rather than structure. Nonetheless, when studies in the mid-20th century suggested that the transient norbornyl cation (C 7 H 11 + ) reacted as though a carbon center had adopted a formally pentacoordinate motif, this nonclassical structural hypothesis engendered tremendous controversy. Scholz et al. (p. 62 ) have now succeeded in characterizing the norbornyl cation by x-ray crystallography and confirm the symmetrical fivefold motif.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference64 articles.

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4. Correspondence - The 2-norbornyl cation revisited

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