Mapping of Functional Groups in Metal-Organic Frameworks-Reference-Cited by-同舟云学术

Mapping of Functional Groups in Metal-Organic Frameworks

Published:2013-08-23 Issue:6148 Volume:341 Page:882-885
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Kong Xueqian¹²,Deng Hexiang³⁴,Yan Fangyong¹⁴,Kim Jihan⁴,Swisher Joseph A.¹⁴,Smit Berend¹³⁴,Yaghi Omar M.³⁴⁵,Reimer Jeffrey A.¹²

Affiliation:

1. Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.

2. Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

3. Department of Chemistry, University of California, Berkeley, CA 94720, USA.

4. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

5. NanoCentury KAIST Institute and Graduate School of Energy, Environment, Water, and Sustainability (World Class University), Daejeon 305-701, Republic of Korea.

Abstract

Mapping Molecular Linkers In metal-organic framework compounds, inorganic centers (metal atoms or clusters) are linked by bidentate organic groups. Normally, the same group is used throughout the structure, but recently, synthesis with linkers bearing different functional groups has produced well-defined materials. Kong et al. (p. 882 , published online 25 July) combined solid-state nuclear magnetic resonance and molecular simulations to map the distributions of linkers in these materials as random, well-mixed, or clustered.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference41 articles.

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4. K. Schmidt-Rohr H. W. Spiess Multidimensional Solid-State NMR and Polymers (Academic Press San Diego CA 1994).

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