Indirect electrochemical titration of sulfur impurities in industrial phosphoric acid

Author:

HAMID Fatima Ezzahra1,Oubaouz Mohamed2,Haddouchy Hassan1,Oukbab Mustapha2,Loughmari Saliha2,Tahiri Youness2,Elqouatli Salah Eddine1,Chtaini Abdelilah2,Erradi Elmostafa2

Affiliation:

1. Faculty of Sciences and Technology, Moulay Ismail University

2. Sultan Moulay Slimane University, FST-BM

Abstract

Abstract

This article explores the corrosion aspects of L316 stainless steel in an environment composed of phosphoric acid extracted from natural phosphates from Morocco, in the presence of sulfate ions. L316 stainless steel is widely used in various industries, but its behavior in the presence of phosphoric acid and sulfate ions has attracted growing interest. The study was carried out using experimental techniques such as electrochemical tests like cyclic voltametry (VC), impedance spectroscopy (EIS) and Taffel curves (VL), surface analysis, and weight loss measurements. The results indicate that the presence of sulfate ions has a significant impact on the corrosion rate of L316 steel in the extracted phosphoric acid medium. Specific corrosion mechanisms were proposed and discussed on the basis of the experimental observations.

Publisher

Research Square Platform LLC

Reference13 articles.

1. Prabhu-Gaunkar, G. V. & Raman, A. Corrosion inhibitors in fertilizer production and handling. In NACE-Int. Corros. Conf. Ser. 1996-mars (1996).

2. Chemically functionalized of 8-hydroxyquinoline derivatives as efficient corrosion inhibition for steel in 1.0 M HCl solution: Experimental and theoretical studies;Galai M;Surf. Interfaces,2020

3. DFT calculations and MC simulations concept of novel quinazolinone derivatives as corrosion inhibitor for mild steel in 1.0 M HCl medium Nordine;Abousalem A;J. Mol. Liq.,2020

4. Corrosion of galvanized steel in dilute Ca (OH)2 solutions (PH 11.1–12.6);Macías A;Br. Corros. J.,1987

5. Acha Hurtado, M. Corrosión Bajo Tensión de Alambres de Acero Pretensado en Medios Neutros con HCO3- y alcalinos con SO4 2-. Thèse de doctorat, Universidad Complutense de Madrid, Madrid, Espagne, octobre 1993 ; p. 321.

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