Bioprospecting and Repurposing of Leaf Biomass to Support Sustainable Biopharmacy: Evaluation of seasonal chemical variations and biological activities of six Eucalyptus essential oils

Author:

Migacz Izabel Pietczak1ORCID,Wang Mei2,Faoro Janaine Alberto Marangoni3,Santos Sidney Mariano dos3,Formagio Anelise Samara Nazari3,Kassuya Candida Aparecida Leite3,Rehman Junaid Ur4,Perera Wilmer Hervet5,Gonçalves Vitória Caroline6,Chaves Douglas Siqueira de Almeida7,Raman Vijayasankar8,Farago Paulo Vitor1,Khan Ikhlas Ahmed9,Manfron Jane10ORCID

Affiliation:

1. Universidade Estadual de Ponta Grossa Departamento de Ciências Farmacêuticas: Universidade Estadual de Ponta Grossa Departamento de Ciencias Farmaceuticas

2. USDA-ARS Natural Products Utilization Research Unit

3. Universidade Federal da Grande Dourados

4. National Center for Natural Products Research

5. Camag Scientific Inc.

6. UEPG: Universidade Estadual de Ponta Grossa

7. UFRRJ: Universidade Federal Rural do Rio de Janeiro

8. USDA-APHIS-PPQ National Identification Services

9. NCNPR: National Center for Natural Products Research

10. Universidade Estadual de Ponta Grossa

Abstract

Abstract

This study focuses on six Eucalyptus species, namely E. badjensis, E. benthamii, E. dunnii, E. grandis, E. globulus, and E. saligna aiming at a sustainable use of their green biomass. These species were grown at the same location and stage of development. Leaf essential oils were extracted by hydrodistillation using a Clevenger apparatus during the four seasons. GC-MS and HPTLC techniques were used to analyze the chemical composition. E. badjensis displayed a consistent composition, with 1,8-cineole being the predominant component. Notably, the proportion of 1,8-cineole in E. badjensis was 77,35% in spring, 69,46% in summer, 95,30% in autumn, and 89,30% in winter. E. globulus also exhibited 1,8-cineole as its primary constituent, with proportions fluctuating slightly across seasons at 84,87%, 79,94%, 81%, and 85,88%, respectively. The proportions and constituents of various species differed significantly. HPTLC was successfully used as a swift technique to monitor the chemical composition of essential oils (EOs) in various Eucalyptus species during the seasonality. GC/MS and HPTLC analysis showed that different Eucalyptus species displayed unique chemical compositions, while both the chemical profile and productivity of all analyzed EOs were affected by seasonality. This finding was demonstrated in the principal components cluster. The analysis of six species has revealed that the EO of E. benthamii is the most potent in thwarting the infestation of Cimex lectularius. Additionally, all six EOs demonstrated antioxidant activity in the ABTS model. EOs of E. benthamii, E. dunnii, and E. grandis showed significant anti-inflammatory activities in experimental models.

Publisher

Springer Science and Business Media LLC

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