Impact of the amount of the gold layer on the tribological performance of the ceramic conversion treated CP-Titanium

Abstract

Abstract Titanium alloys are characterised by poor tribological properties, and a ceramic TiO2 layer formed on the surface can greatly improve its performance. By pre-depositing a gold layer on the titanium surface, the gold particles promote the outward diffusion of titanium in the ceramic conversion treatment to react with the inward-coming oxygen to form a compact titanium dioxide layer. The surface morphology, microstructure, phase constituents were characterised by SEM/EDX and XRD. The adhesion o the oxide layers were assessed by a scratch test. The distribution of gold particles in the oxide layer can enhance the surface hardness and reduce friction and wear against a WC ball in the reciprocal tribological test. The ceramic conversion process can be accelerated efficiently at 620-660°C, and the more gold pre-deposited, the thicker the oxide layer.