S vacancy in MoS 2 nanosheets induce H 2 O cleavage: a new era for 2D nanozyme

Author:

Wang Jin1,Ren Wenyu1,Wang Yi1,Zhang Dun1,Ju Peng2,Dou Kunpeng3

Affiliation:

1. Chinese Academy of Sciences

2. First Institute of Oceanography

3. Ocean University of China

Abstract

Abstract Nanozyme is a promising approach in treating pollution in drinking water sources. 2D MoS2 nanosheets, with abundant active sites and Lewis acid sites, exhibits outstanding peroxidase-like and antibacterial activities. Verified by density functional calculation, S vacancies in 2D MoS2 nanosheets can cleavage H2O to yield H+ and ·OH. The spontaneous generation of acid environment and oxygen free radicals enables 2D MoS2 nanosheets to be effectively exploited in the depuration of polluted water, creating a new era for multifunctional nanozymes.

Publisher

Research Square Platform LLC

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