Affiliation:
1. Akita Prefectural University - Honjo Campus: Akita Kenritsu Daigaku - Honjo Campus
Abstract
Abstract
Enhanced interfacial polarization is one of the most effective methods to achieve efficient electromagnetic wave absorbing (EMA) performance. In this study, we propose a cladding morphology modulation strategy for the preparation of high-performance PPy/MWCNTs(PC) by controlling the polymerization cladding morphology of PPy through acid doping using an in-situ polymerization method. By constructing a 3D network structure with rough surface, a large number of interfaces and pore spaces are generated to increase the multiple reflections and scattering of electromagnetic wave energy, improve the interfacial polarization of the material, and enhance the polarization relaxation process. Meanwhile, the 3D conductive network generated by the cladding provides a channel for electron transfer between MWCNTs and PPy nanoparticles and PC nanorods, which improves the conductivity loss of the material and allows more electromagnetic wave to be dissipated in the form of thermal energy. With the doping acid of p-toluenesulfonic(TsOH), the EMA absorption performance of PC composites can reach a maximum reflection loss(RLmin) of -60.21 dB at the frequency of 8.24 GHz, and the best effective bandwidth (EABmax) of 5.04 GHz for single thickness and 14.08 GHz for full thickness (EABsun), providing excellent EMA performance.
Publisher
Research Square Platform LLC