Synthesis of allylamines from Baylis-Hillman acetates using DBU under solvent free condition

Author:

Khom Sonam Tashi1,Saikia Pranjit1,Muzaddadi Ijaz Ullah1,Murugan Arumugam1,Yadav Nagendra Nath Nath1ORCID

Affiliation:

1. North Eastern Regional Institute of Science and Technology

Abstract

Abstract A simple, new and solvent free route to the regioselective and stereoselective synthesis of (E)- and (Z)- allylamines has been achieved by the reaction of Baylis-Hillman acetates with various nitrogen nucleophiles in the presence of 1,8-diazabicyclo(5.4.0)undec-7-ene (DBU). This method requires very short reaction time and accomplished by SN2ʹ nucleophilic substitution pathway.

Publisher

Research Square Platform LLC

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