Humidity and Oxygen Effects on Photochromic Properties of MTO/ITO Thin Films

Author:

Inoue Shuhei1,Matsuo Ippei2,Matsumura Yukihiko2

Affiliation:

1. Kindai University

2. Hiroshima University

Abstract

Abstract

The study investigates the photochromic properties of magnesium tin oxide (MTO) films deposited on indium tin oxide (ITO) substrates under various environmental conditions. The photochromic behavior involves the transition of the material to a black state upon ultraviolet (UV) irradiation and its return to transparency upon heating. MTO films deposited on ITO substrates exhibited significant coloration upon UV exposure, with a notable decrease in visible light transmittance. Structural analysis revealed the formation of metallic indium at the MTO/ITO interface during UV irradiation, suggesting a complex reaction mechanism involving oxygen and hydrogen radicals. Investigations into the effects of atmospheric gases and humidity on UV-induced coloration indicated that moisture plays a crucial role in promoting photochromism, while the presence of oxygen influences the degree of coloration. The study provides insights into the underlying processes driving the photochromic phenomenon in MTO/ITO systems and underscores the importance of environmental factors in modulating their optical properties. Further research is warranted to fully elucidate the role of oxygen and its derivatives in the photochromic mechanism of MTO films for potential applications in energy storage devices.

Publisher

Research Square Platform LLC

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