Preparation and characterization of H3PMo11O39@SiO2@g-C3N4 nanocomposite and using as heterogeneous effective catalyst for one-pot green synthesis of 4-hydropyran derivatives under solvent-free conditions-Reference-Cited by-同舟云学术

Preparation and characterization of H3PMo11O39@SiO2@g-C3N4 nanocomposite and using as heterogeneous effective catalyst for one-pot green synthesis of 4-hydropyran derivatives under solvent-free conditions

Published:2024-04-29 Issue: Volume: Page:
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Author:

Bahmanziyari Maryam¹,Naeimi Hossein¹

Affiliation:

1. University of Kashan

Abstract

A novel Brønsted acidic nanocomposite, H₃PMo₁₁O₃₉@SiO₂@g-C₃N₄ has easily prepared. This nanocomposite has characterized and identified using a Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDX). Three-component condensation reaction of aldehyde, malononitrile, and dimedone carried out in the presence of the H₃PMo₁₁O₃₉@SiO₂@g-C₃N₄ nanocomposite as a green catalyst under solvent-free conditions at room temperature. The experimental results show that the 4-hydropyran derivatives obtained in high yields and very short reaction times. Easy workup, reusability, and stability of the green catalyst are noteworthy advantages of this method. Moreover, this heterogeneous catalyst can be satisfactorily recovered by simple filtration and reused at least five times without loss of activity.

Publisher

Research Square Platform LLC

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