Tunable TiAl 3 -Reinforced Aluminum Matrix Composites via In-Situ Reactive Printing: Insights from Operando Synchrotron Analysis and Microstructural Characterization

Author:

Tian Chenxi1,Singh Kaushalendra1,Wakai Akane1,Dass Adrita1,Bustillos Jenniffer1,Chuang Andrew C.2,Moridi Atieh1

Affiliation:

1. Cornell University

2. Argonne National Laboratory

Abstract

Abstract

Additive-manufactured TiAl3-reinforced aluminum matrix composite (AMC) materials were fabricated by forming TiAl3 whiskers from the in-situ reaction between aluminum (Al) and titanium (Ti). The composite demonstrates enhancement of mechanical strength with tunable ductility compared to unreinforced material while using a feedstock mixture of only commercially available Al and Ti powder of standard size distribution. The enhancement to mechanical strength is attributed to both load transfer from the strong TiAl3 reinforcement and the Hall-Petch strengthening from the refined grain size of the Al matrix. Operando synchrotron analysis of the in-situ reactive printing (IRP) process, coupled with postmortem microstructural characterizations, reveals that the dispersed TiAl3 whiskers refine Al grain size by promoting heterogeneous nucleation through in-situ inoculation. This study validates the capability of IRP to strengthen the integration of material and geometry design in additive manufacturing by enabling the fabrication of highly tunable AMC.

Publisher

Research Square Platform LLC

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