Effect of the glycerol dispersant on the structure, electrical transport and magnetoresistive properties of La0.67Ca0.33MnO3 ceramics prepared by the sol-gel routine

Abstract

In this paper, the sol-gel technique is employed to synthesize polycrystalline La_0.67Ca_0.33MnO₃ (LCMO) ceramics, where methanol is chosen as the solvent. The crystal structure, morphology, as well as electrical and magnetoresistive properties. Moreover, the effect of amount of the dispersant glycerol on the properties of LCMO ceramics is studied. X-ray diffraction (XRD) results showed that all samples crystallized in single phases with orthogonal perovskite structure (pnma space group), without any detectable impurity phases. Results reveal that the grain size of LCMO ceramics exhibits an initial increase followed by a decrease, accompanied by a similar behavior in the temperature coefficient of resistance (TCR) and magnetoresistance (MR). When the volume ratio of glycerol and methanol reached 2%, the grain size is determined to be 7.30 µm, with TCR value of 25.02% K^− 1 at T = 263.2 K, and MR value recorded at 55.40%. The study elucidates the influence of glycerol on LCMO polycrystalline ceramics and optimize the fabrication process, thereby improve the electric transport property and magnetoresistance.