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η 3 -allyl-Pd(II) complexes of 2-, 3- and 4-pyridylmethyl- coumarin esters

  • Published:2022-09-16 Issue: Volume: Page:
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Author:

González-Montiel Simplicio1,Velázquez-Jiménez René1,Segovia-Pérez Raúl1,Fragoso-Soto Willyfredo1,Martínez-Otero Diego2,Andrade-López Noemí1,Salazar-Pereda Verónica1,Cruz-Borbolla Julián1

Affiliation:

1. Universidad Autónoma del Estado de Hidalgo

2. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM

Abstract

Abstract A series of 2-, 3- and 4-pyridylmethyl-coumarin esters ligands (1–3) and their η3-allyl palladium complexes (1-Pd – 3-Pd) have been designed, synthetized and characterized. NMR analysis of compounds 1-Pd – 3-Pd indicated the presence of the allyl fragment. The molecular structure of 2, 3 and 1-Pd was determined by X-ray crystallographic analysis. The molecular structure 1-Pd reveals that coumarin ligand (2) is coordinated to the palladium center via a monodentate fashion through the nitrogen atom of the pyridinyl fragment while the allyl group is binding via a η3 fashion in an overall square-planar geometry completed with a chloride atom. An investigation of intermolecular interactions in crystal packing via a Hirshfeld surfaces and fingerprint plots analyses showed a wide variety of intermolecular contacts such as H•••O and H•••N hydrogen bonding, π•••π stacking, C–H•••π and carbonyl (lone pair)•••π interactions that generated polymeric arrays.

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Research Square Platform LLC

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