Affiliation:
1. China University of Mining and Technology
Abstract
Abstract
The limited application of high sulfur coal (HSC) and the increasing severity of copper pollution in solution are two pressing issues. To alleviate such issues, a sulfur self-doped coal-based adsorbent (HSC@ZnCl2) was obtained by pyrolysis-activation (850 ℃, 60 min holding time) of HSC and ZnCl2 with a mass ratio of 1:0.5. Characterizations including scanning electron microscope (SEM) and X-ray diffraction (XRD) confirmed that HSC@ZnCl2 exhibited part rough and part smooth surface, and sulfur in HSC could combine with Zn2+ to form the adsorption site ZnS. Cu2+ adsorption experiments indicated that the adsorption process followed the Sips isothermal adsorption model and the pseudo-second-order kinetic model with an adsorption capacity of 12 mg/g. Zeta potential and X-ray photoelectron spectroscopy were performed to elucidate the adsorption mechanism of Cu2+ onto HSC@ZnCl2, which primarily involved complexation, electrostatic attraction and surface precipitation. Funding from this work indicate that preparation of sulfur self-doped coal-based adsorbent prepared from high sulfur coal are a promising method for its large-scale utilization.
Publisher
Research Square Platform LLC