Salts containing different amino acids: L-argininium (+) sarcosine halogenides

Author:

Tonoyan Gayane S.1,Giester Gerald2,Petrosyan Aram M.1

Affiliation:

1. NAS of Armenia

2. University of Vienna

Abstract

Abstract Recently we have discovered a new class of amino acids salts containing different amino acids. In the present paper we report crystal structures of three isostructural salts: l-argininium(+) sarcosine chloride (I), l-argininium(+) sarcosine bromide (II) and l-argininium(+) sarcosine iodide (III), formed by slow evaporation at room temperature from aqueous solutions containing stoichiometric ratios of components. The compounds crystallize in the polar space group P21 with two formula units in the asymmetric unit. The structures are stabilized due to N-H···O and N-H···X (X = Cl, Br, I) hydrogen bonds. Infrared spectra of all three crystals are shown and discussed.

Publisher

Research Square Platform LLC

Reference32 articles.

1. Fleck M, Petrosyan AM (2014) Salts of Amino Acids: Crystallization, Structure and Properties. Springer, Dordrecht

2. Petrosyan AM, Giester G, Tonoyan GS, Ghazaryan VV, Fleck M A new class of amino acids salts. Abstracts of the 3rd German Polish Conference on Crystal Growth, March 17–21, 2019, Poznań, Poland, p. 57. http://gpccg2019.put.poznan.pl/wp-content/uploads/2019/03/ABSTRACTS_ONLINE.pdf

3. Salts containing different amino acids: Three types salts of l-arginine containing glycine, dimethylglycine or β-alanine;Petrosyan AM;J Mol Struct,2021

4. Salts containing different amino acids: Salts with β-alaninium l-proline dimeric cation;Tonoyan GS;J Mol Struct,2022

5. X-Ray analysis of l-arginine hydrohalides, Current science;Mazumdar SK,1964

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