Investigation of the main regularities of glycolysis of polycarbonate plastic during catalysis by basic agents

Author:

Kurneshova Tatyana A.1ORCID,Dzhabarov Georgy V.1,Sapunov Valentin N.1,Kozlovskiy Roman A.1,Voronov Mikhail S.1,Sergeenkova Maria P.1,Varlamova Elena V.1,Antoshkina Evgeniya P.2

Affiliation:

1. D Mendeleev University of Chemical Technology of Russia: Rossijskij himiko-tehnologiceskij universitet imeni D I Mendeleeva

2. A N Nesmeyanov Institute of Organoelement Compounds RAS: FGBUN Institut elementoorganiceskih soedinenij imeni A N Nesmeanova Rossijskoj akademii nauk

Abstract

Abstract This research focuses on analyzing how different primary catalysts affect the glycolysis of plastic made from bisphenol A (PC) polycarbonate. It was found that the process of chemical decomposition of PC leads to the formation of products with high added value: bisphenol A (PC monomer, BPA), BPA, and ethylene carbonate or ethylene glycol co-ethers (BPA monohydroxyethyl ether, MHE-BPA; BPA bishydroxyethyl ether, BHE-BPA). A quantitative assessment of the yields of the reaction products was also carried out. The yield of products at 100% PC conversion was 33% for BPA, 50% for MHE-BPA, and 17% for BHE-BPA. The effectiveness of using various alkalis depending on the type of metal was also compared within the context of this investigation.

Publisher

Research Square Platform LLC

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