Abstract
Abstract
The effects of the macrocycle structure and the medium nature on photodecomposition under UV irradiation of different Indium phthalocyanines: the diindium tripledecker phthalocyanine, In2Pc3 (1), sandwich indium phthalocyanine, InPc2 (2) and iodoindium phthalocyanine, InPcI (3) in benzene, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), dichloromethane (DCM) and 1-chloronaphtalene has been studied. The rate of decay of absorption is explained by a decomposition reaction which is of first-order kinetics with respect to the phthalocyanines concentration. In general, in the present of ligand I− in phthalocyanine InPcI enhance the rate of decomposition.
Publisher
Research Square Platform LLC
Reference35 articles.
1. 1. C.C. Leznoff, A.B.P. Lever (Eds.), Phthalocyanines: Properties and Applications, vols. 1–4, VCH Publishers, Inc., New York (1989–1996)
2. 2. J. Janczak, R. Kubiak, Inorg. Chim. Acta. 376, 28–35, (2011) https://doi.org/10.1016/j.ica.2011.05.030.
3. 3. J. Janczak, R. Kubiak, Inorg. Chem. Acta, 288, 174–180, (1999)
4. 4. J. Janczak, R. Kubiak J. Chem. Soc., Dalton Trans. 3809–3812, (1993) https://doi.org/10.1039/DT9930003809.
5. 5. J. Janczak, R. Kubiak, A. Jezierski, Inorg. Chem. 34 3505–3508,(1995) https://doi.org/10.1021/ic00117-020.