The influence of combined active fillers on the properties of elastomeric materials for eco-friendly tyres

Abstract

Reinforcing of elastomers by the addition of various nanofillers has led to significant improvements in elastomer properties, and therefore, to the increase of potentials for use as suitable materials for special applications. The aim of this study was to investigate the effects of combinations of two active fillers (carbon black and synthesized silica (50/0; 35/15; 25/25; 15/35; 0/50; phr)) on the morphology, curing, as well as thermal, dynamic-mechanical and mechanical properties of nanocomposites based on the styrene-butadiene rubber as the network precursor. Based on SEM results, the largest agglomerates were observed in the structure of the nanocomposite containing 25 phr of carbon black and 25 phr of SiO2. Determination of curing characteristics indicated that the minimum torque at 100, 150 and 160?C had higher magnitudes for the compounds with silica filler, which is in accordance with the tendency of SiO2 to form filler-filler interactions. Values of the scorch time and the optimal time of crosslinking increased by increasing the silica phr content in the fillers mixture. It could be thus supposed that the fraction of occluded and trapped chains in the structure of elastomer reinforced by SiO2 is higher due to the almost 2-fold higher value of the silica NDBP number as compared to the NDBP number of carbon black particles. On the basis of MDSC results, it was assessed that the addition of combined active fillers had negligible effects on the glass transition temperature, registered at about -47?C for all tested samples. The obtained DMA data, concerning storage moduli in the temperature range from -20 to 0?C, (characteristic for "Payne" effect) are very significant for predictions of the properties of the tyre tread such as the slip resistance on the road on ice and in the wet conditions. The increase of silica content in the combined filler induced a decrease of the dynamic mechanical loss factor of prepared nanocomposites in the temperature range from 40 to 80?C. The obtained results are very important for the structuring of elastomeric materials aimed for production of tyres with reduced rolling resistance and fuel consumption. The elastomer containing the highest content of carbon black showed the highest value of the tensile strength (21.8 MPa). The abrasion resistance of the synthesized nanocomposites increased as the silica content was reduced in the combined fillers.