Sorption of Cu2+ and Co2+ ions from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study

Author:

Lazarevic Slavica1ORCID,Jankovic-Castvan Ivona1,Radovanovic Zeljko1ORCID,Potkonjak Branislav2,Janackovic Djordje1,Petrovic Rada1

Affiliation:

1. Faculty of Technology and Metallurgy, Belgrade

2. Institute of Chemistry, Technology and Metallurgy, Belgrade

Abstract

The efficiency of natural sepiolite for the removal of Cu2+ and Co2+ ions from aqueous solution was determined using the batch method. The sorption experiments were performed as a function of the initial metal concentration, the equilibration time and temperature. Thermodynamic parameters, such as enthalpy, free energy and entropy, were calculated from the temperature dependent sorption isotherms and these values showed that the sorption of the investigated metals onto sepiolite was endothermic. The pseudo-second order kinetic model provides the best correlation of the experimental kinetic data.

Publisher

National Library of Serbia

Subject

General Chemistry

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