The function of nano layer in enhancing the thermal conductivity of TiO2/water nanofluids
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Published:2024
Issue:3 Part B
Volume:28
Page:2539-2549
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ISSN:0354-9836
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Container-title:Thermal Science
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language:en
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Short-container-title:Therm sci
Author:
Huang Xiaoyan1, Zhang Xiaohui1, Qing Shan1
Affiliation:
1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, China + National local Joint Engineering Research Center of Energy Saving and Environmental Protection Technology in Metallurgy and Chemical Engineering Industry, Kunming University of Science and Technology, Kunming, China
Abstract
Nanoparticles have the capability to effectively improve the thermal
conductivity of base fluids, thus improving the heat transfer coefficient of
heat transfer systems. In this study, a non-equilibrium molecular dynamics
(NEMD) method based on the Fourier law is employed to study the thermal
conductivity of TiO2 (r-TiO2)/water nanofluids with temperatures ranging
between303K and 333K and volume fractions in the range of1-2%. The ordered
layer structure as a shell is analyzed and its influence is surveyed by
calculating the number density and radial distribution function (RDF).The
results revealed that a clear, solid-like nanolayer of about 0.5 nm can be
observed around the nanoparticle. In this regard, the thickness of the
nanolayer is less affected by variations in volume fraction and temperature.
The g(r) values and the number density decreased with the increase
in temperature. Additionally, the g(r) values and the number density at the level
of the nanolayer were much higher compared to those at other parts. This
indicates the existence of more water molecules in the nanolayer, thereby
reducing contact thermal resistance and improving thermal conductivity.
Macroscopically, the thermal conductivity increases with the increase
in volume fraction. It was found that the increase in the volume fraction from
1%to 2%at303Kresulted in an increase in the effective thermal conductivity
from1.027 and 1.042, respectively. In other words, the thermal conductivity
of the nanofluid was 2.7% and 4.2% higher than that of the base liquid under
the same conditions.
Publisher
National Library of Serbia
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