Synthesis and dyeing performance of some amphiphilic naphthalimide azo disperse dyes on polyester fabrics

Author:

Ameuru Umar1,Yakubu Mohammed1,Bello Kasali1,Nkeonye Peter1,Halimehjani Azim2

Affiliation:

1. Department of Polymer and Textile Engineering, Ahmadu Bello University, Zaria, Nigeria

2. Faculty of Chemistry, Kharazmi University, Tehran, Iran

Abstract

A series of monoazo disperse dyes were synthesized by coupling diazotized 4-amino-N-dodecyl-1,8-naphthalimide with N,N-dialkyl anilines and naphthol derivatives. The synthesized intermediates and the dyes were characterized using FTIR, 1H-NMR, 13C-NMR, mass spectroscopy and elemental analysis (CHN). Visible absorption spectra of the dyes were examined in solvents of different polarities. The electronic absorption spectra cover a wavelength (?max) range of 515-535 nm in DMF at uniformly absorption intensity between 1.59-3.00?104 L mol-1 cm-1. The dyes gave deep and bright intense hues of light violet, maroon, pink and neon red on polyester fabrics. The dyes generally showed good washing and perspiration rating but poor to moderate light fastness properties on woven polyester fabric and could be recommended for commercial outlets.

Publisher

National Library of Serbia

Subject

General Chemistry

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