Preparation and modification of itaconic anhydride-methyl methacrylate copolymers-Reference-Cited by-同舟云学术

Preparation and modification of itaconic anhydride-methyl methacrylate copolymers

Published:2007 Issue:12 Volume:72 Page:1507-1514
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Milovanovic Milos¹,Trifunovic Snezana²^ORCID,Katsikas Lynne³,Popovic Ivanka³^ORCID

Affiliation:

1. Institut za hemiju, tehnologiju i metalurgiju, Beograd

2. Hemijski fakultet, Beograd

3. Tehnološko-metalurški fakultet, Beograd

Abstract

The free radical copolymerisation of itaconic anhydride and methyl methacrylate in solution was studied at 60 ?C. The copolymer composition was determined by 1H-NMR spectroscopy and the obtained monomer reactivity ratios were calculated, rITA = 1.35?0.11; rMMA = 0.22?0.22 (by the Fineman-Ross method) and rITA = 1.27?0.38; rMMA = 0.10?0.05 (by the Mayo-Lewis method). The synthesised copolymers were modified by reaction with di-n-butyl amine. The copolymer composition after amidation was determined by elemental analysis via the nitrogen content. Amidation of the anhydride units in the copolymers with di-n-butyl amine resulted in complete conversion to itaconamic acid.

Publisher

National Library of Serbia

Subject

General Chemistry

Reference10 articles.

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