Whey desalination using polymer and inorganic membranes: Operation conditions

Author:

Myronchuk Valerii1,Zmievskii Yurii1,Dzyazko Yuliya2,Rozhdestvenska Ludmila2,Zakharov Vladimir1

Affiliation:

1. National University of Food Technologies of the MES of Ukraine, Kyiv, Ukraine

2. V.I. Vernadskii Institute of General & Inorganic Chemistry of the NAS of Ukraine, Kyiv, Ukraine

Abstract

Electrodialytic desalination of cheese whey was carried out using a pair of polymer cation exchange (Nafion 117) and inorganic membranes. The ceramic separator was modified with nanocomposite containing hydrated zirconium dioxide and basic bismuth nitrate. This amphoteric filler provides anion exchange ability of the composite membrane. This property is realized when at least one side of the membrane is in contact with an acidic solution. Ion transport through the membranes was shown to be determined by current, whey acidity, and also by composition of the solution in the concentration compartment of the electrochemical cell. It was shown that whey desalination occurred under overlimiting current. Acidification of whey and decrease of the acid content in the concentrate suppress ion transport. The electrodialysis of whey and nanofiltration permeate allowed removal of up to 80% of the mineral components in 5 h and 40 min, respectively. Preliminary ozonation of the permeate increased the rate of desalination.

Publisher

National Library of Serbia

Subject

General Engineering

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