Influence of Er3+ doping on the mechanical and thermophysical properties of (ErxY1-x)3Al5O12 ceramics
-
Published:2023
Issue:1
Volume:17
Page:23-30
-
ISSN:1820-6131
-
Container-title:Processing and Application of Ceramics
-
language:en
-
Short-container-title:PAC
Author:
Wang Xuanli1, Xing Jinxin2, Xie Min2, Mu Rende3, Song Xiwen2
Affiliation:
1. Inner Mongolia Key Laboratory of Advanced Ceramics and Device, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China + Collaborative Innovation Center of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, China 2. Inner Mongolia Key Laboratory of Advanced Ceramics and Device, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China 3. Key Laboratory of Advanced Corrosion and Protection for Aviation Materials, Beijing Institute of Aeronautical Materials, Aero Engine Corporation of China, Beijing, China
Abstract
In this work, Er3+ was selected to replace Y3+ in the yttrium aluminium
garnet (YAG) in order to improve its mechanical and thermophysical
properties. A series of (ErxY1-x)3Al5O12 (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9 and
1.0) ceramics were prepared by solid-state synthesis method at 1000 ?C and
finally sintered at 1600 ?C for 5 h. The microstructure and morphology of
the prepared ceramics were investigated. The results showed that all Er3+
doped Y3Al5O12 ceramics exhibited single garnet-type YAG phase and good
compactness. With the increase of Er3+ doping concentration, the thermal
conductivity of the (ErxY1-x)3Al5O12 ceramics decreased slowly and then
increased subsequently. Among the investigated specimens, the
(Er0.7Y0.3)3Al5O12 had the lowest thermal conductivity (1.51W/m?K, at 1000
?C), which was about 28% lower than that of the pure YAG (2.1W/m?K, at 1000
?C). As the Er3+ doping concentration increased, the thermal expansion
coefficient of the (ErxY1-x)3Al5O12 ceramics hardly changed, remaining
around 9.08 ? 10?6 K?1 at 1200 ?C. Moreover, when the Er3+ doping
concentration exceeded 0.5, the mechanical properties of the
(ErxY1-x)3Al5O12 ceramics increased suddenly. Specifically, the hardness
increased from 14.28 to 16.53GPa and the bending strength increased from
231.74 to 324.49MPa.
Publisher
National Library of Serbia
Subject
Ceramics and Composites
Reference23 articles.
1. J.J. Yan, G. Yan, H.Y. Chen, Z.Y. Liu, L. Yang, Y.C. Zhou, “Real-time detection of damage evolution and failure of EB-PVD thermal barrier coatings using an environmental simulator with high-temperature and high-speed rotation”, Surface Coat. Technol., 439 (2022) 128416. 2. Z. Meng, Y. Liu, Y. Li, X. He, “The performance evaluation for thermal protection of turbine vane with film cooling and thermal barrier coating”, Appl. Therm. Eng., 210 (2022) 118405. 3. Z. Shen, Z. Liu, G. Liu, L. He, R. Mu, Z. Xu, “The morphology, thermal property, and failure mechanism of GdNdZrO thermal barrier coatings by EB-PVD”, Int. J. Appl. Ceram. Tec., 18 (2021) 1623-1629. 4. P. Zhao, H. Zheng, G. Li, Y. Geng, Y. Xiao, H. Guo, P. Peng, “Mechanical properties, thermophysical properties and electronic structure of Yb3+ or Ce4+-doped La2Zr2O7 based TBCs”, J. Rare Earth., 41 (2023) 588-598. 5. F. Zhou, Y. Wang, M. Liu, C. Deng, Y. Li, Y. Wang, X. Zhang, “Bonding strength and thermal conductivity of novel nanostructured La2(Zr0.75Ce0.25)2O7/8YSZ coatings”, Appl. Surf. Sci., 481 (2019) 460-465.
|
|