Affiliation:
1. School of Materials Science and Engineering, Xi’an University of Technology, Xi’an, China
Abstract
Li4SiO4 has been widely studied as tritium breeder and high temperature CO2
capture material. Tritium breeding rate and CO2 adsorption capacity are
closely related to lithium content and microstructure. Since high sintering
temperatures result in grain coarsening and lithium sublimation, it is a
great challenge to prepare Li4SiO4 ceramics with a satisfactory mechanical
strength at low sintering temperature. In this work, mesoporous silica was
used as Si source to prepare Li4SiO4 spheres. The mesoporous structure might
provide more reaction sites for lithium ions, thereby facilitating the
reaction between LiOH and mesoporous silica. The sintering temperature of
Li4SiO4 spheres was greatly reduced by using mesoporous silica as Si source.
The Li4SiO4 spheres with a homogenous fine-grained microstructure (the
average grain size of 2.2 ?m) and high crushing load (41.65N) could be
obtained at 675?C.
Publisher
National Library of Serbia