Affiliation:
1. Institute of Chemistry and Chemical Engineering, Jinan University, Jinan, Institute of Chemistry and Chemical Engineering, Shandong University, Jinan
2. Institute of Chemistry and Chemical Engineering, Jinan University, Jinan
3. Institute of Chemistry and Chemical Engineering, Shandong University, Jinan
Abstract
The complex [La(NO 3)3(TBMA)2] (TBMA = N,N,N?,N?-tetrabutylmalonamide) was prepared by the extraction method and characterized by single-crystal X-ray diffraction. The complex consists of two bidentate TBMA extractant and three bidentate nitrate ions coordinated to a La3+ ion. The lanthanum(III) is 10-coordinate, being bonded to four oxygen atoms of the malonamides and six oxygen atoms of the three nitrates. The crystal data are as follows C38H76N7O13La, Mr = 977.97, triclinic system, space group P 1, a = 1.3025(12), b = 1.4353(14), c = 0.4871(13) nm, ? = 70.025(17), ? = 71.411(19), ? = 84.017(18)?, V = 2.476(4) nm3, Z = 2, F(000) = 1028, D = 1.312 g.cm-3, R 1 = 0.0833, wR 2 = 0.1471.
Publisher
National Library of Serbia
Cited by
2 articles.
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