Development of an analytical model for copper heap leaching from secondary sulfides in chloride media in an industrial environment

Author:

Saldaña Manuel1,Salinas-Rodríguez Eleazar2,Castillo Jonathan3,Peña-Graf Felipe4,Roldán Francisca5

Affiliation:

1. Faculty of Engineering and Architecture, Universidad Arturo Prat, Iquique, Chile + Departamento de Ingeniería Química y Procesos de Minerales, Facultad de Ingeniería, Universidad de Antofagasta, Antofagasta, Chile

2. Área Académica de Ciencias de la Tierra y Materiales, Universidad Autónoma del Estado de Hidalgo, Mineral de la Reforma, Hidalgo, Mexico

3. Departamento de Ingeniería en Metalurgia, Universidad de Atacama, Copiapó, Chile

4. Escuela de Ingeniería, Universidad Católica del Norte, Coquimbo, Chile

5. Centro de Investigación para la Gestión Integrada del Riesgo de Desastres (CIGIDEN), Departamento de Ciencias Geológicas. Universidad Católica del Norte (UCN), Antofagasta, Chile

Abstract

In multivariate analysis, a predictive model is a mathematical/statistical model that relates a set of independent variables to dependent or response variable(s). This work presents a descriptive model that explains copper recovery from secondary sulfide minerals (chalcocite) taking into account the effects of time, heap height, superficial velocity of leaching flow, chloride concentration, particle size, porosity, and effective diffusivity of the solute within particle pores. Copper recovery is then modelled by a system of first-order differential equations. The results indicated that the heap height and superficial velocity of leaching flow are the most critical independent variables while the others are less influential under operational conditions applied. In the present study representative adjustment parameters are obtained, so that the model could be used to explore copper recovery in chloride media as a part of the extended value chain of the copper sulfides processing.

Publisher

National Library of Serbia

Subject

General Chemical Engineering,General Chemistry

Reference70 articles.

1. Flanagan DM. Copper. In Mineral Commodity Summaries 2021. Reston, VA, USA: U.S. Geological Survey; 2021; 52-3. ISBN 9781411343986.

2. Villela D, Kutscher C, Castillo E. Sulfuros primarios: desafíos y oportunidades. Comisión Chilena del Cobre (COCHILCO). Santiago, Chile: 2017.

3. ICSG. Copper: Preliminary Data for January 2020. International Copper Study Group (ICSG): Lisbon, Portugal: 2020.

4. Pérez K, Toro N, Gálvez E, Robles P, Wilson R, Navarra A. Environmental, economic and technological factors affecting Chilean copper smelters - A critical review. J Mat Res Technol. 2021; 15: 213-25. https: //doi.org/10.1016/j.jmrt.2021.08.007

5. Navarra A, Wilson R, Parra R, Toro N, Ross A, Nave JC, Mackey PJ. Quantitative methods to support data acquisition modernization within copper smelters. Processes 2020; 8(11): 1-22. https: //doi.org/10.3390/pr8111478

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