Affiliation:
1. Faculty of Chemistry, Belgrade
2. Faculty of Sciences, Novi Sad
Abstract
In this work we reported syntheses and characterization of two novel
compounds of adamantane-1-sulfonic acid (1-AdSO3H) with cobalt(II) and
cadmium(II), respectively. The result of the single crystal X-ray analysis of
compounds revealed that adamantane-1-sulfonate (1-AdSO3 -) in monoanionic
form plays a different role in investigated compounds. Namely, while in
compound [Co(H2O)6](1-AdSO3)2 six water molecules are coordinated to
cobalt(II) ion and 1-AdSO3 - serves as a counter ion, in compound
[Cd(H2O)4(1-AdSO3)2] two molecules of 1-AdSO3 - are trans-coordinated to the
cadmium(II) ion as monodentate (O) ligand and other coordination sites are
occupied by water molecules. The obtained compounds showed a moderate
activity against Artemia salina.
Publisher
National Library of Serbia
Cited by
2 articles.
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