Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid

Author:

Djordjevic Milena1,Jeremic Dejan1ORCID,Andjelkovic Katarina1,Gruden-Pavlovic Maja1,Divjakovic Vladimir2,Sumar-Ristovic Maja1ORCID,Brceski Ilija1ORCID

Affiliation:

1. Faculty of Chemistry, Belgrade

2. Faculty of Sciences, Novi Sad

Abstract

In this work we reported syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO3H) with cobalt(II) and cadmium(II), respectively. The result of the single crystal X-ray analysis of compounds revealed that adamantane-1-sulfonate (1-AdSO3 -) in monoanionic form plays a different role in investigated compounds. Namely, while in compound [Co(H2O)6](1-AdSO3)2 six water molecules are coordinated to cobalt(II) ion and 1-AdSO3 - serves as a counter ion, in compound [Cd(H2O)4(1-AdSO3)2] two molecules of 1-AdSO3 - are trans-coordinated to the cadmium(II) ion as monodentate (O) ligand and other coordination sites are occupied by water molecules. The obtained compounds showed a moderate activity against Artemia salina.

Publisher

National Library of Serbia

Subject

General Chemistry

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