Affiliation:
1. Faculty of Technology and Metallurgy, Department of General and Inorganic Chemistry, Belgrade
2. Faculty of Technology and Metallurgy, Innovation Center, Belgrade
3. Faculty of Sciences, Novi Sad
Abstract
The title compound, (Hdipya)(H3pyr), where Hdipya is protonated
2,2?-dipyridilamine and H3pyr is monoanion of pyromellytic acid (H4pyr), was
obtained from the reaction mixture containing Zn(II) ions, dipya, Na4pyr
(the molar ratio 2 : 2 : 1) and HNO3. The products (micro- and
single-crystalline) were characterized by X-ray structure determination,
FT-IR spectroscopy and TG/DSC analysis. The most striking structural feature
of (Hdipya)(H3pyr) are short inter- and extremely short intramolecular
hydrogen bonds. These bonds mutually connect cations and anions making thin
layers parallel to the crystallographic (223) plane. Also, quite unusual,
linear proton-bound polymeric {H(H2pyr)-}n anions were identified in the
structure. The results of crystal structure determination are compared with
FT-IR and TG/DSC data. The low position of nas(COO) vibration at 1660 cm-1
is in accordance with strong hydrogen bonding. This value can be used as a
measure of C=O bond order, which is calculated to be 1.81.
Funder
Ministry of Education, Science and Technological Development of the Republic of Serbia
Publisher
National Library of Serbia
Cited by
1 articles.
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