Affiliation:
1. Institute of Catalysis, Bulgarian Academy of Sciences, 'Acad. G. Bonchev', Sofia, Bulgaria
Abstract
The initial stage of transformation of pyrite to Fe(II)-sulfate as a result of mechanical milling is studied by X-ray powder diffraction (XRD), Moessbauer spectroscopy (MS), Infrared (IR) and X-ray photoelectron spectroscopy (XPS) techniques. A degree of conversion of 0.071 is achieved in the time interval of 0 36 min. The kinetic data satisfy the equation of a shrinking core reaction 1-(1-?)1/3=kt. The reaction is of the first order. The calculated rate constant is k=6.434.10-4 min-1. .
Publisher
National Library of Serbia
Subject
Materials Chemistry,Metals and Alloys,Mechanics of Materials,Geotechnical Engineering and Engineering Geology
Cited by
3 articles.
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