Use of the SSF equations in the Kojima-Moon-Ochi thermodynamic consistency test of isothermal vapour-liquid equilibrium data
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Published:2000
Issue:12
Volume:65
Page:877-889
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ISSN:0352-5139
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Container-title:Journal of the Serbian Chemical Society
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language:en
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Short-container-title:JSCS
Author:
Jelic Jelena1,
Tasic Aleksandar1,
Djordjevic Bojan1,
Serbanovic Slobodan1
Affiliation:
1. Faculty of Technology and Metallurgy, Belgrade
Abstract
The Kojima-Moon-Ochi (KMO) thermodynamic consistency test of vapour-liquid
equilibrium (VLE) measurements for 32 isothermal data sets of binary systems
of various complexity was applied using two fitting equations: the
Redlich-Kister equation and the Sum of Symmetrical Functions. It was shown
that the enhanced reliability of the fitting of the experimental data can
change the conclusions drawn on their thermodynamic consistency in those
cases of VLE data sets that are estimated to be near the border of
consistency.
Publisher
National Library of Serbia
Subject
General Chemistry