Molecular orbital study of the oxidation of steroidal phenols into quinols and epoxyquinols-Reference-Cited by-同舟云学术

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Molecular orbital study of the oxidation of steroidal phenols into quinols and epoxyquinols

Published:2000 Issue:7 Volume:65 Page:491-496
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Markovic Zoran¹^ORCID,Solaja Bogdan²^ORCID,Milic Dragan²,Juranic Ivan³^ORCID,Gasic Miroslav⁴

Affiliation:

1. Faculty of Science, Chemistry Department, Kragujevac

2. Faculty of Chemistry, Belgrade + Institute of Chemistry, Technology and Metallurgy, Belgrade

3. Faculty of Chemistry, Belgrade

4. Institute of Chemistry, Technology and Metallurgy, Belgrade

Abstract

The MO study showed that the radical oxidation of phenols into quinols occurs readily. Further radical oxidation (in the m-CPBA/(BzO)2/hv system) of quinols occurs through appropriate biradical species with an activation energy of 79.5 kJ/mol yielding syn-epoxyquinols. The stereochemical outcome presented in this study is in full agreement with the experimental results.

Publisher

National Library of Serbia

Subject

General Chemistry

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Iron salt-promoted oxidation of steroidal phenols by m-chloroperbenzoic acid: a route to possible antitumor agents;RSC Advances;2022

2. Mechanistic investigations on the antioxidant action of a neuroprotective estrogen derivative;Steroids;2008-03

3. Synthesis and antiproliferative activity of A-ring aromatised and conduritol-like steroidal compounds;Steroids;2005-12

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