Study of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO

Author:

Peltekov A.B.1,Boyanov B.S.1

Affiliation:

1. University of Plovdiv “Paisii Hilendarski”, Department of Chemical Technology, Plovdiv, Bulgaria

Abstract

The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and M?ssbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200?C and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed.

Publisher

National Library of Serbia

Subject

Materials Chemistry,Metals and Alloys,Mechanics of Materials,Geotechnical Engineering and Engineering Geology

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