N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems-Reference-Cited by-同舟云学术

N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems

Published:2010 Issue:2 Volume:75 Page:157-163
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Jovic Branislav¹,Nikolic Aleksandar¹,Davidovic Erna²,Petrovic Slobodan³

Affiliation:

1. Prirodno-matematički fakultet, Novi Sad

2. 'Lavoslav Ružička' Polytehnic of Vukovar, Vukovar, Croatia

3. Tehnološko-metalurški fakultet, Beograd

Abstract

This paper reports the results of an FT-IR and NIR study of N-methylformamide in carbon tetrachloride solution in presence of ethers as the O-electron donors, i.e., diethyl ether (DEE), diisopropyl ether (DiPE), methyl t- -butyl ether (MtBE), dibutyl ether (DBE), dipentyl ether (DPE), tetrahydrofuran (THF) and tetrahydropyran (THP). The spectroscopic characteristics of the N-H???O hydrogen bonded complexes are given. In addition, the equilibrium constants for 1:1 complex formation were determined at 25?C using Mid-IR and NIR measurements.

Publisher

National Library of Serbia

Subject

General Chemistry

Reference11 articles.

1. NH…π hydrogen bonding: Infrared study of N-cyclohexylformamide-aromatic donor systems

2. NH…π hydrogen bonding: FTIR study of N-butylpropionamides-aromatic donor systems

3. N–H⋯O hydrogen bonding: FT IR, NIR and 1H NMR study of N-methylpropionamide – Cyclic ether systems

4. N–H...O hydrogen bonding. FT-IR, NIR and 1H NMR study of N-methylpropionamide – Dialkyl ether systems

5. Infinite Dilution Activity Coefficients of Organic Solutes in N,N-Diethyldodecanamide

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