Synthesis, X-ray structure and DFT calculation of magnetic properties of binuclear Ni(II) complex with tridentate hydrazone-based ligand-Reference-Cited by-同舟云学术

Synthesis, X-ray structure and DFT calculation of magnetic properties of binuclear Ni(II) complex with tridentate hydrazone-based ligand

Published:2020 Issue:10 Volume:85 Page:1279-1290
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Keskic Tanja¹,Radanovic Dusanka²,Pevec Andrej³,Turel Iztok³,Gruden Maja¹^ORCID,Andjelkovic Katarina¹,Mitic Dragana⁴^ORCID,Zlatar Matija²^ORCID,Cobeljic Bozidar¹^ORCID

Affiliation:

1. Faculty of Chemistry, University of Belgrade, Belgrade, Serbia

2. Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Belgrade, Serbia

3. Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ljubljana, Slovenia

4. Innovation center of the Faculty of Chemistry, University of Belgrade, Belgrade, Serbia

Abstract

Abstract: Binuclear double end-on azido bridged Ni(II) complex (1) with composition [Ni2L2(?-1,1-N3)2(N3)2]?6H2O, (L = (E)-N,N,N-trimethyl-2-oxo-2-(2- -(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-amin) was synthesized and characterized by single-crystal X-ray diffraction method. Ni(II) ions are hexacoordinated with the tridentate heteroaromatic hydrazone-based ligand and three azido ligands (one terminal and two are end-on bridges). DFT calculations revealed that coupling between two Ni(II) centers is ferromagnetic in agreement with binuclear Ni(II) complexes with similar structures.

Funder

Ministry of Education, Science and Technological Development of the Republic of Serbia

Publisher

National Library of Serbia

Subject

General Chemistry

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Nickel(II) and nickel(III) thiosemicarbazone and hydrazone complexes: An unexpected journey;Inorganic Chemistry Communications;2023-12

2. Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation;Journal of Molecular Structure;2022-10

3. Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents;JBIC Journal of Biological Inorganic Chemistry;2021-09-06

4. Synthesis, characterization, computational, antioxidant and fluorescence properties of novel 1,3,5-trimesic hydrazones derivatives;Heliyon;2021-09