Synthetic study on the angular triquinanes-Reference-Cited by-同舟云学术

Synthetic study on the angular triquinanes

Published:2023 Issue:10 Volume:88 Page:975-983
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Stjepanovic Mihailo¹,Jankovic Aleksandar²^ORCID,Vulovic Bojan¹^ORCID,Matovic Radomir²^ORCID,Saicic Radomir³^ORCID

Affiliation:

1. University of Belgrade, Faculty of Chemistry, Belgrade, Serbia

2. ICTM, Center for Chemistry, Belgrade, Serbia

3. University of Belgrade, Faculty of Chemistry, Belgrade, Serbia + Serbian Academy of Sciences and Arts, Belgrade, Serbia

Abstract

The synthesis of an angular triquinane, which could serve as a suitable platform for the synthesis of several natural products (panaginsene, silphinene, senoxydene) is described. The synthesis is based on two consecutive cyclopentene annulations, where alkenes were used as latent carbonyl functionalities (via Wacker reaction), and cyclopentenone annulation was effected by aldol condensation.

Funder

Ministry of Education, Science and Technological Development of the Republic of Serbia

Publisher

National Library of Serbia

Subject

General Chemistry

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