Ca(II) complexes of tetraazamacrocycles derived from 3, 4-hexenedione and diaminoalkanes

Author:

Prasad R.N.1,Agrawal M.1,Malhotra S.1

Affiliation:

1. Department of Chemistry, University of Rajasthan, Jaipur, India

Abstract

Ca(II) macrocyclic complexes [(Et4[n]tetraeneN4)CaX2]?(where n = 14, 16, 20 24, 32, X = Cl-, NCS-) have been synthesized via cyclocondensation of 3,4-hexanedione with aliphatic diamines, such as 1,3-diaminopropane 1,4-diaminobutane, 1,6-diaminohexane, 1,8-diaminooctane or 1,12-diaminododecane. The synthesized complexes were characterized by elemental analyses, conductance measurements and IR and 1H-NMR spectroscopy.

Publisher

National Library of Serbia

Subject

General Chemistry

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