Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex-Reference-Cited by-同舟云学术

Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex

Published:2005 Issue:5 Volume:70 Page:681-686
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Bugarcic Zorica¹,Novokmet Slobodan²^ORCID,Kostic Vladan¹

Affiliation:

1. University of Kragujevac, Faculty of Science, Department of Chemistry, Kragujevac

2. University of Erlangen-Nürnberg, Institute of Inorganic Chemistry, Erlangen, Germany

Abstract

The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2[12H2O] reacts with primary and secondary benzylic alcohols whereby good yields of the corresponding carbonyl compounds are obtained. The presented method provides for the selective oxidation of the benzylic hydroxyl group in compounds containing other types of alcoholic functional groups.

Publisher

National Library of Serbia

Subject

General Chemistry

Reference20 articles.

1. Copper-Dioxygen Complexes. Inorganic and Bioinorganic Perspectives

2. Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction

3. Making and Breaking the Dioxygen O−O Bond: New Insights from Studies of Synthetic Copper Complexes

4. Aerobic epoxidation of olefins with ruthenium porphyrin catalysts

5. Aerobic oxidation of cyclohexene with a phosphine-ruthenium(II)-aquo catalyst

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