Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane-Reference-Cited by-同舟云学术

Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane

Published:2006 Issue:10 Volume:71 Page:1049-1059
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Zhong H.¹,Zeng R.¹

Affiliation:

1. Provincial key laboratory of coordination chemistry, Jinggangshan University, Jian, College of chemistry and chemical engineering, Jinggangshan University, Jian

Abstract

Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPSmethods. Their catalytic behavior in the total oxidation of hexane was examined. The following activity order was found LaSrCoO4 > LaSrNiO4 > LaSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxygen, particle size and BET surface area. .

Publisher

National Library of Serbia

Subject

General Chemistry

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