Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3

Author:

Khosa-Kaleem Muhammad1,Mazhar Muhammad1,Ali Saqib1,Dastgir Sarim1,Parvez Masood2,Malik Abdul3

Affiliation:

1. Department of Chemistry, Quaid-i-Azam University, Islamabad

2. Department of Chemistry, University of Calgary, University Drive NW, Calgary, Alberta

3. HEJ Research Institute of Chemistry, International Centre for Chemical Sciences, University of Karachi, Karachi

Abstract

Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR (1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity. .

Publisher

National Library of Serbia

Subject

General Chemistry

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