Affiliation:
1. Department of Chemistry, Central College Campus, Bangalore University, Bangalore, India
Abstract
2-Trimethylsilyl-1,3,3-trimethylcyclopentene and
2-trimethylsilyl-1,3,3-trimethylcyclohexene were prepared in good yields by
the Wurtz-Fittig coupling reaction of the corresponding
2-iodo-1,3,3-trimethylcyclopentene and 2-chloro-1,3,3-trimethylcyclohexene
with metallic sodium and chlorotrimethylsilane in anhydrous ether solvent.
The Friedel-Crafts acylation reaction of
2-trimethylsilyl-1,3,3-trimethylcyclopentene with six different acid
chlorides and the novel preparation of six
alkyl/alkenyl/aryl-(1?,3?,3?-trimethylcyclopentenyl)ketones is reported.
Publisher
National Library of Serbia
Cited by
2 articles.
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