Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)
-
Published:2022-06-30
Issue:2
Volume:13
Page:196-205
-
ISSN:2153-2257
-
Container-title:European Journal of Chemistry
-
language:en
-
Short-container-title:Eur J Chem
Author:
Ndoye Cheikh1ORCID, Excoffier Gregory2ORCID, Seck Gorgui Awa1ORCID, Diouf Ousmane1ORCID, Thiam IbraIbrahima Elhadji1ORCID, Sidibe Mamadou2ORCID, Gaye Mohamed1ORCID
Affiliation:
1. Department of Chemistry, Faculty of Sciences and Technology, University Cheikh Anta Diop, Dakar, 10700, Sénégal 2. Spectropole, Fédération des Sciences Chimiques de Marseille, Aix-Marseille Université, Marseille, 13397, France
Abstract
The reactions of Schiff base 1-(1-hydroxypropan-2-ylidene)thiosemicarbazide (H2L), with salt of thiocyanate metal (II) (Co, Ni, or Zn), provided one dinuclear and two new mononuclear complexes, formulated respectively as {[Co(LH)2]2·[Co(NCS)4] ·2(MeOH)} (1), {[Ni(H2L)2]·[(NCS)2]} (2) and [Zn(H2L)(NCS)2] (3). These compounds have been studied and characterized by elemental analysis, infrared, and ultraviolet-visible (UV-vis) spectroscopies. The structures of the three complexes have been resolved by X-ray crystallography technique. The dinuclear complex 1 crystallizes in the orthorhombic space group Fdd2 with the following unit cell parameters a = 33.1524 (3) Å, b = 19.3780 (2) Å, c = 13.2533 (2) Å, V = 8514.28 (17) Å3, Z = 16, R1 = 0.025 and wR2 = 0.063, the mononuclear complex 2 crystallizes in the monoclinic space group P21/n with the following unit cell parameters a = 11.5752 (1) Å, b = 12.3253 (1) Å, c = 14.2257 (2) Å, β = 106.855 (1)°, V = 1942 (4) Å3, Z = 4, R1 = 0.038 and wR2 = 0.106 and the mononuclear complex 3 crystallizes in the monoclinic space group P21/c with the following unit cell parameters a = 6.1121 (2) Å, b = 26.8272 (7) Å, c = 8.0292 (2) Å, β = 99.876 (3)°, V = 1297.04 (6) Å3, Z = 4, R1 = 0.026 and wR2 = 0.057. The asymmetric unit of Complex 1 contains one cationic unit in which the ligand acts in its monodeprotonated form in tridentate fashion and one half of the anionic unit containing two thiocyanate co-ligands. In complexes 2 and 3, the ligand acts in its neutral form in a tridentate manner. In complex 2, two ligand molecules coordinate the Ni(II) center, and the thiocyanate moieties remains uncoordinated. In complex 3, the Zn(II) is coordinated by one ligand molecule and two thiocyanate groups through their nitrogen atoms. Numerous hydrogen bonds consolidated the structures of complexes 1, 2, and 3 in a three-dimensional network.
Publisher
European Journal of Chemistry
Reference62 articles.
1. [1]. Hosseinpoor, H.; Moghadam Farid, S.; Iraji, A.; Askari, S.; Edraki, N.; Hosseini, S.; Jamshidzadeh, A.; Larijani, B.; Attarroshan, M.; Pirhadi, S.; Mahdavi, M.; Khoshneviszadeh, M. Anti-melanogenesis and anti-tyrosinase properties of aryl-substituted acetamides of phenoxy methyl triazole conjugated with thiosemicarbazide: Design, synthesis and biological evaluations. Bioorg. Chem. 2021, 114, 104979. 2. [2]. Tokalı, F. S.; Taslimi, P.; Usanmaz, H.; Karaman, M.; Şendil, K. Synthesis, characterization, biological activity and molecular docking studies of novel schiff bases derived from thiosemicarbazide: Biochemical and computational approach. J. Mol. Struct. 2021, 1231, 129666. 3. [3]. Bakherad, Z.; Mohammadi-Khanaposhtani, M.; Sadeghi-Aliabadi, H.; Rezaei, S.; Fassihi, A.; Bakherad, M.; Rastegar, H.; Biglar, M.; Saghaie, L.; Larijani, B.; Mahdavi, M. New thiosemicarbazide-1,2,3-triazole hybrids as potent α-glucosidase inhibitors: Design, synthesis, and biological evaluation. J. Mol. Struct. 2019, 1192, 192-200. 4. [4]. Aboseada, H. A.; Hassanien, M. M.; El-Sayed, I. H.; Saad, E. A. Schiff base 4-ethyl-1-(pyridin-2-yl) thiosemicarbazide up-regulates the antioxidant status and inhibits the progression of Ehrlich solid tumor in mice. Biochem. Biophys. Res. Commun. 2021, 573, 42-47. 5. [5]. Altalhi, A. A.; Hashem, H. E.; Negm, N. A.; Mohamed, E. A.; Azmy, E. M. Synthesis, characterization, computational study, and screening of novel 1-phenyl-4-(2-phenylacetyl)-thiosemicarbazide derivatives for their antioxidant and antimicrobial activities. J. Mol. Liq. 2021, 333, 115977.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
|
|