Abstract
The use of supramolecular interactions to control and direct excited-state reactivity is described, with emphasis on the author's contributions in this area. The systems are based on the multiple-point hydrogen-bonding molecular recognition motif present in the melamine–barbituric
acid system, and are designed to operate in solution phase. Despite the weak nature of non-covalent interactions, control of high energy intermediates such as excited cinnamantes, stilbenes, or fullerenes is possible. These results demonstrate the particular sensitivity of short-lived electronically
excited molecules to their environment, and particularly to the mutual orientation of the reactants.
Subject
General Medicine,General Chemistry
Cited by
13 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Synthesis, growth, experimental, and theoretical characterization of 6-amino-1H-pyrimidine-2,4-dione dimethylacetamide single crystal;Chinese Journal of Physics;2022-03
2. Antiglycation Activity of N, N-Diethylthiobarbiturates Derivatives;Letters in Drug Design & Discovery;2020-04-25
3. Synthesis, Molecular Modeling and Biological Evaluation of 5-arylidene-N,N-diethylthiobarbiturates as Potential α-glucosidase Inhibitors;Medicinal Chemistry;2019-02-12
4. Conversion of 1,3-Dimethyl-5-(Arylazo)-6-Amino-Uracils to 1,3-Dimethyl-5-(Arylazo)-Barbituric Acids: Spectroscopic Characterization, Photophysical Property and Determination of pKaof the Products;Journal of the Chinese Chemical Society;2016-05-06
5. Synthesis, NMR, FT-IR, X-ray structural characterization, DFT analysis and isomerism aspects of 5-(2,6-dichlorobenzylidene)pyrimidine-2,4,6(1H,3H,5H)-trione;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2015-08