Clay Supported Ammonium Nitrate “Clayan”: A New Reagent for Selective Nitration of Arenes

Author:

Meshram H. M.1,Ganesh Y. S. S.1,Madhavi A. V.1,Eshwaraiah B.1,Yadav J. S.1,Gunasekar D.2

Affiliation:

1. a Indian Institute of Chemical Technology , Hyderabad, Andhra Pradesh, India

2. b Department of Chemistry , S. V. University , Andhra Pradesh, India

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference22 articles.

1. Clay supported ammonium nitrate “Clayan”: A mild and eco-friendly reagent for dethioacetalization

2. Microwave thermolysis IV: Selective deprotection of MPM ethers using clay supported ammonium nitrate “clayan” in dry media

3. Clayan is prepared following the earlier procedure: To a solution of ammonium nitrate (5 g) in distilled water (70 mL) was added montmorillonite K10 (Aldrich Chemical Co.) 5 g in portions at room temperature and the suspension stirred for 1 h. water is removed using rotary evaporator at 50–60°C under reduced pressure and thew resulting solid was dried under vacuum at 40°C for 2 h and the reagent stored in a stoppered bottle. Detailed experimental procedure may be obtained from the Indian patent No: 56/Del/99

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