Hygrothermal ageing performance of high temperature vulcanised silicone rubber and its degradation mechanism

Author:

Deng Yu1ORCID,Peng Bo2,Liu Zheyuan1,Du Yujun1ORCID,Zhou Songsong1,Liu Jinghua2,Yu Xinzhe1,Zhou Jun1

Affiliation:

1. State Key Laboratory of Power Grid Environmental Protection (China Electric Power Research Institute) Beijing China

2. State Grid Corporation of China Beijing China

Abstract

AbstractHigh temperature vulcanised silicone rubber (SR) has excellent hydrophobicity and thus is widely applied both in indoor and outdoor insulation. According to the analysis of different experimental ageing tests and field investigation of SR, temperature and humidity are considered to be the fundamental factors during degradation. Hygrothermal ageing was proposed in this study to simulate the chalking state of the SR, finally leading to the irreversible degradation far below the thermal decomposition temperature. The variation of morphology, hardness and polydimethylsiloxane (PDMS) content was quantified during the yearlong hygrothermal ageing test. It is implied that the gradual process of whitening and hardening are accompanied by the decline of the PDMS content. Finally, ageing delamination in SR and its degradation mechanism were proposed.

Funder

State Grid Corporation of China

Publisher

Institution of Engineering and Technology (IET)

Subject

Electrical and Electronic Engineering,Energy Engineering and Power Technology

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