Heterogeneous Asymmetric Β-C-H Functionalization of Aldehydes Under O2 Catalyzed by Hydroxide-Layered Fe(Iii) Sites Synergistic with Confined Interlayer Amine

Author:

An Zhe,Han Hongbo,Zhong Jianning,Zhang Jian,Zhu Yanru,Shu Xin,Song Hongyan,Wang Wenlong,Zheng Lirong,Qing Ming,He Jing

Publisher

Elsevier BV

Subject

General Earth and Planetary Sciences,General Environmental Science

Reference53 articles.

1. Under O 2 atmosphere, 25.2% of 1a conversion was respectively obtained in 6 h and 12 h with the input dosage of 5.0 (olive, left) and 2.5 mol% (olive, right), giving a similar turnover frequency (TOF) value of 0.75 h -1 . While under N 2 atmosphere, 18% of 1a conversion was obtained in 6 h with the input dosage of 5.0 mol% (orange, left), while 9% conversion of 1a in 12 h with the input dosage of 2.5 mol% (orange, right);M species, respectively. For Mg 3 AlFe-Pro-LDHs used under N 2 (Mg 3 AlFe-Pro-LDHs-N 2 ), the M-O-H peak shifts to lower binding energy of 531.3 eV from 531.7 eV before used, and the corresponding ratio of

2. Transition Metal-Catalyzed C-H Activation Reactions: Diastereoselectivity and Enantioselectivity;R Giri;Chem. Soc. Rev,2009

3. Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes;C G Newton;Chem. Rev,2017

4. Asymmetric Iron-Catalyzed C-H Alkylation Enabled by Remote Ligand Meta-Substitution;J Loup;Angew. Chem. Int. Ed,2017

5. An Efficient Enantioselective Method for Asymmetric Michael Addition of Nitroalkanes to ?,?-Unsaturated Aldehydes;Y Wang;Chem. Commun,2008

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