Synthesis, Structural Distortion, and Magnetic Property of Complex Perovskites Amn0.2m0.8o2.6n0.4 (a = Sr, Ba; M = Nb, Ta)

Author:

Kim Young-Il,Avdeev Maxim

Publisher

Elsevier BV

Subject

General Earth and Planetary Sciences,General Environmental Science

Reference51 articles.

1. The joint Rietveld refinement of the synchrotron XRD and ND patterns revealed that BaMn 0.2 M 0.8 O 2.6 N 0.4 have orthorhombic (Pnma) symmetries with moderate intra-octahedral distortions and minute octahedral tilting distortions. The unusual structural distortions of BaMn 0.2 M 0.8 O 2.6 N 0.4 , as compared with other Ba-based perovskite oxynitrides, are similar to the contrast between SrMn 0.2 M 0.8 O 2.6 N 0.4 and other Sr-based perovskite oxynitrides, and are ascribed to the enhanced covalency contributed from Mn 2+ . Conforming to the general attribute of oxynitride phases;M = Nb;Ta ? Sr:Ta ? Ba:Nb ? Sr:Nb. The band gaps of AMn 0.2 M 0.8 O 2.6 N 0.4 were also dependent on the cation composition, and decreased in an order, Sr:Ta ? Ba:Ta ? Sr:Nb ? Ba:Nb, where the type of M played the more important role

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