Synthesis of (Vx,Ti1-X)3alc2 Max Phases with X=0-0.9 and Their Etching to Two-Dimensional Mxenes

Author:

Kotasthane Vrushali,Tan Zeyi,Holta Dustin E.,Micci-Barreca Stefano,Lutkenhaus Jodie L.,Green Micah,Radovic Miladin

Publisher

Elsevier BV

Reference60 articles.

1. Electrical conductivity measurements for the vacuum-filtered (V x ,Ti 1-x ) 3 C 2 T z MXene nanosheet (x=0-90) films measured by a four-point probe are shown in Figure 8 and Table S7. Interestingly, the Ti-rich compositions of (V x ,Ti 1-x ) 3 C 2 T z MXenes, specifically for x=0, 0.1, and 0.3 show relatively higher conductivity values than the compositions with x=0;For the highest V-rich composition (x=0.9), an increase in conductivity was observed. However, all conductivity values for the

2. This trend in conductivity values observed for (V x ,Ti 1-x ) 3 C 2 T z MXenes is also comparable to the trend predicted and measured for their "211' counterparts, (V x ,Ti 1-x ) 2 CT z , reported in the literature.[41] However, conductivities reported here for (V x ,Ti 1-x ) 3 C 2 T z are almost an order of magnitude higher than those reported for (V x ,Ti 1-x ) 2 CT z , for compositions with lower and higher V contents;the range of 10 5 S/m order-ofmagnitude range

3. The MN+ 1AXN phases: A new class of solids: Thermodynamically stable nanolaminates;M W Barsoum;Progress in solid state chemistry,2000

4. On the chemical diversity of the MAX phases;M Sokol;Trends in Chemistry,2019

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