Abstract
Natural gas, which mainly consists of methane, is a good fuel for vehicles. Metal-organic frameworks (MOF) have attracted much attention as a new group of adsorbent materials in natural gas storage. MOF structures form various networks by connecting secondary structural units composed of metal ions and organic binders. These regular materials have high porosity and have high design capabilities. This feature has made MOFs suitable for special applications in trapping and absorbing various materials. The investigation of these materials has focused on the absorption of pure methane, although natural gas contains a small amount of larger hydrocarbons such as ethane and propane, which have greater absorption than methane. This Manuscript presents an overview of the current state of the metal-organic framework for methane storage.