Affiliation:
1. Otto Schott Institute of Materials Research , Friedrich-Schiller-Universität Jena, Löbdergraben 32, 07743 Jena , Germany; e-mail:
Abstract
Abstract
Microstructural evolution of GexPb1–xTe (x=0.5, 0.87, 0.9) alloys with respect to spinodal decomposition and continuous/discontinuous precipitation is investigated. Solution treatment at 630 °C for 10 days leads to a single-phase grain structure with homogeneous concentration distribution. In Ge0.5Pb0.5Te, after aging at 300, 400, and 450 °C for 3 days a lamellar spinodally decomposed microstructure was observed. For the alloys with higher Ge content, a diffusion controlled decomposition of the supersaturated solid solution occurs, during which two different microstructures form either simultaneously or separately. Inside the miscibility gap, but outside the spinodal line, a nucleation and growth mechanism leads to continuous and discontinuous precipitation at the grain boundaries, followed by continuous precipitation in the grain interior.
Subject
Metals and Alloys,Mechanics of Materials,Condensed Matter Physics,Electronic, Optical and Magnetic Materials